Lynn R. Mazzoleni

Lynn R. Mazzoleni



Assistant Professor, Chemistry

  • PhD, University of Nevada, Reno

Research Motivation

Atmospheric aerosols and clouds play important roles in determining the Earth’s climate. Trace gases and aerosols, constitute only a tiny fraction of the atmospheric mass, however they interfere with the solar radiative transfer through the atmosphere. Along with molecular scattering and absorption from gases, aerosol particles and clouds determine in part what fraction of solar radiation reaches the Earth’s surface and what fraction of it returns to space. Aerosol particles are especially complex. Particles can exert both a direct effect by reflecting and absorbing solar radiation. They also promote an indirect effect by influencing cloud properties and lifetimes. Water uptake by particles is responsible for haze formation, cloud formation, and can affect the amount of water vapor in the atmosphere, thus it is a key indirect effect. Overall, the uncertainty in aerosol radiative forcing is considerably larger than that due to greenhouse gases (IPCC 1996, 2007). This limits our scientific ability to predict future surface temperature changes and to unambiguously detect a greenhouse warming signal. Organic aerosol components arise from a combination of anthropogenic and biogenic sources. These include but are not limited to: biomass combustion, vehicle emissions, meat cooking, secondary reactions, and emissions from plants and animals. The components of aerosol may either by emitted to the atmosphere as fine particulate matter or as gases.

Dr. Mazzoleni's primary research interests are to identify organic aerosol constituents from a variety of atmospheric environments. Her research group uses advanced mass spectrometry (MS) techniques to identify organic molecules from atmospheric complex mixtures. Her group has participated in a number of ambient and laboratory studies and is complying a large database of molecular observations to unravel the complex nature of ambient aerosol. Currently, Dr. Mazzoleni is the lead investigator of collaborative research carried out at the Pico Mountain Observatory in the Azores (PT) to understand the chemical, physical, and radiative properties of North Atlantic free tropospheric aerosol sponsored by the National Science Foundation. Dr. Mazzoleni is also co-investigator with Dr. Raymond Shaw for the development of a turbulent cloud chamber also sponsored by the National Science Foundation. The cloud chamber will facilitate novel studies of aqueous aerosol and cloud processing of ambient water soluble gases.

Links of Interest

Research Interests

  • Understanding the identities, occurrence, and transformation of aerosol organic compounds
  • Identifying organic aerosol constituents from a variety of atmospheric environments
  • Exploration of new LC column chemistries with ultrahigh pressure pumps for fast and thorough separations
  • Aqueous reaction pathways

Recent Publications

  • Zhao, Y., A.G. Hallar, and L.R. Mazzoleni, Atmospheric Organic Matter in Clouds: Exact Masses and Molecular Formula Identification using Ultrahigh Resolution FT-ICR Mass Spectrometry, Atmospheric Chemistry and Physics Discussion, 13, 20561-20610, doi:10.5194/acpd-13-20561-2013, 2013. Accepted October 29, 2013 for publication in Atmospheric Chemistry and Physics. Read More
  • Hallar, A.G., D.H. Lowenthal, V. Samburova, G. Chirokova, L.R. Mazzoleni, B. Zielinska, I.B. McCubbin, C. Dodson, T. Kristensen, Overview of Hygroscopic Properties of Aerosol Organics Study at the Storm Peak Laboratory, Journal of Geophysical Research, Vol. 118, doi: 10.1002/jgrd.50373, 2013. Read More
  • Kristensen, T.B., H. Wex, B. Nekat, J.K. Nøjgaard, D. van Pinxteren, D.H. Lowenthal, L.R. Mazzoleni, K. Dieckmann, C. Bender Koch, T.F. Mentel, H. Herrmann, A.G. Hallar, D. Stratmann, and M. Bilde. Hygroscopic Growth and CCN Activity of HULIS from Different Environments, Journal of Geophysical Research, Vol. 117, D22203, doi:10.1029/2012JD018249, 2012 Read More
  • Kundu, S., R. Fisseha, A.L. Putman, T.A. Rahn, and L.R. Mazzoleni, High Molecular Weight SOA Formation during Limonene Ozonolysis: Insights from Ultrahigh-Resolution FT-ICR Mass Spectrometry Characterization, Atmospheric Chemistry and Physics, Vol. 12, 5523–5536, 2012. Read More
  • Mazzoleni, L.R., P. Saranjampour, M.M. Dalbec, V. Samburova, B. Zielinska, A.G. Hallar, D. Lowenthal, and S. Kohl, Identification of Water-Soluble Organic Carbon in Nonurban Organic Aerosols using Ultrahigh-Resolution FT-ICR Mass Spectrometry: Organic Anions, Environmental Chemistry, Vol. 9(3) 285-297, 2012. Invited Special Issue Paper Read More
  • LeClair, J.P., J.L. Collett and L.R. Mazzoleni, Fragmentation Analysis of Water-Soluble Atmospheric Organic Matter using Ultrahigh-Resolution Mass Spectrometry, Environmental Science and Technology, Vol. 46 (8), pp. 4312–4322, 2012. Read More
  • Putman, A.L., J.H. Offenberg, R. Fisseha, S. Kundu, T.A. Rahn, and L.R. Mazzoleni, Ultrahigh-Resolution FT-ICR Mass Spectrometry Characterization of a-Pinene Ozonolysis SOA, Atmospheric Environment, Vol. 46, pp. 164-172, 2012. Read More
  • Kroll, J. H., N.D. Donahue, J.L. Jimenez, S.H. Kessler, M.R. Canagaratna, K.R. Wilson, K.E. Altieri, L.R. Mazzoleni, A.S. Wozniak, H. Bluhm, E.R. Mysak, J.D. Smith, C.E. Kolb, and D.R. Worsnop, Carbon Oxidation State as a Metric for Describing the Chemistry of Atmospheric Organic Aerosol, Nature Chemistry, Vol. 3(2), pp. 133-139, 2011. Read More
  • Mazzoleni, L.R., B.M. Ehrmann, X. Shen, A.G. Marshall, and J.L. Collett, Water-Soluble Atmospheric Organic Matter in Fog Water: Exact Masses and Chemical Formula Identification by Ultrahigh Resolution FT-ICR Mass Spectrometry, Environmental Science and Technology, Vol. 44 (10), pp. 3690–3697, 2010. Read More

Recent Funding

  • Mazzoleni, L.R., C. Mazzoleni, R.C. Owen, N. Urban, S. Olsen, and D. Helmig, Collaborative Research: Chemical, Physical, and Radiative Properties of North Atlantic Free Tropospheric Aerosol after Long-range Transport, NSF Atmospheric Chemistry Program, 2011-2014.
  • Shaw, R., W. Cantrell, C. Mazzoleni and L.R. Mazzoleni, Development of a Turbulent Cloud Chamber, NSF Major Research Instrumentation, 2010-2013.
  • Hallar, A.G., D.H. Lowenthal, B. Zielinska, L.R. Mazzoleni, S. Clegg, D. Collins, Collaborative Research: Hygroscopic Properties of Aerosol Organics, NSF Atmospheric Chemistry Program, 2009-2012.
  • Rahn, T., L.R. Mazzoleni, R.M. Cory, T.E. Larson, Isotopic Tracer for Climate-Relevant Secondary Organic Aerosol Components, Los Alamos National Laboratory, Laboratory Directed Research and Development-Exploratory Research, 2008-2011, Subcontracts to Michigan Technological University, 2009-2011.

Teaching Experience

  • CH1140 – Introduction to Organic, Inorganic & Biochemistry
  • CH1170 – University Chemistry II-GOB (Formerly CH1140)
  • CH4222 – Bioanalytical Chemistry with Bioanalytical Chemistry Laboratory
  • CH4290/CH6290 – Advanced Mass Spectrometry Methods
  • ATM5200/CH4800/CH6800 – Chemistry of Aerosols/Hydrometeors